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Lesson 5-5

Molecular and Empirical Formulas


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     By now you should know that a molecular formula is a group of elemental symbols, and possibly subscript numbers, which represent the composition of a molecule.  The molecular formula shows you how many of each atom can be found in a certain molecule.  Some examples of molecular formulas, that you are most likely familiar with, are shown in table 5-5a.

Table 5-5a - Some Molecular Formulas and the Information they Convey

Formula

Composition

H2O

Total of 3 atoms in each molecule - 1 oxygen and 2 hydrogen

O2

Total of 2 atoms in each molecule - 2 oxygen atoms

CO2

Total of 3 atoms in each molecule - 1 carbon and 2 oxygen

C6H12O6

Total of 24 atoms in each molecule - 6 carbon, 12 hydrogen, and 6 oxygen.

     While the molecular formula shows the molecule as it actually exists, the empirical formula for a compound shows the simplest whole number ratio for the elements in the compounds.  To find the empirical formula for a compound, find the largest whole number that can be divided into each of the subscripts evenly.  If no number will go into any of the subscripts evenly, then the empirical formula and the molecular formula for the compound are the same.  Table 5-5b shows examples of some empirical and molecular formulas.

Table 5-5b - Comparing Empirical and Molecular Formulas

Compound

Molecular Formula

Empirical Formula

Water H2O H2O
Hydrogen Peroxide H2O2 HO
Glucose C6H12O6 CH2O
Methane CH4 CH4
Ethane C2H6 CH3
Octane C8H18 C4H9

 


Molecular and Empirical Formulas Quizzes

 

Molecular and Empirical Formulas Worksheets

Worksheet 5-5a - Determining the Empirical Formula

Please forward all questions, comments and criticisms to Gregory L. Curran.
© Copyright 2004 Fordham Preparatory School, All Rights Reserved.
Last Modified February 07, 2008